Liliane attended Ghana International School, Aburi Girls Secondary School and the University of Ghana Medical School. She has worked as a Medical Officer at the Korle-Bu and La Polyclinics. She started her training in Anesthesiology in the UK and Ireland. After relocating to Houston to join her husband, Dr Samuel Borquaye, she completed her Residency in Anesthesiology at UTMB, Galveston. She then joined the UTMB Dept. of Anesthesiology after residency and worked there until 2013, when she joined Northstar Anesthesia. She currently works at St Joseph Hospital, Houston as a Staff Anesthesiologist.
She and her husband Sam have two young adult daughters. She enjoys taking care of her family and is ready for new challenges.